Crystal structure of the true nasicon: Na3Zr2Si2PO12

For the first time, the results of single crystal determination of the true Nasicon are given. The structure refinement yielded the following composition: Na_3.09(8)Zr_2.01(1)P_0.91Si_2.09O₁₂. Evidence of the total occupancy of the Zr octahedron is found, displaying that only the Si/P non-stoechiometry mechanism is present in the Nasicon crystal.For the two temperatures which have been investigated (R.T. and 623K), the structures are very close to that of the Nasicon analog: Na₃Sc₂P₃O₁₂. However the Si/P substitution prevents the sodium long range ordering even in the monoclinic low temperature phase and therefore the cross over to the rhombohedral symmetry only involves very small atomic displacements. For both structures, a new sodium position (mid-Na) is displayed in the conduction channel, intermediate between the usual Na(1) and Na(2) sites.     

粗壮女贞及其产品营养成分与活性成分比较

该文以粗壮女贞为研究对象,通过标准方法分别对原叶（Ligustrum robustum(Roxb.) Blume,LR）及其产品（Ligustrum robustum(Roxb.) Blume Products,LRP）中的营养成分与活性成分进行分析比较。结果表明：一般营养成分中,LR的蛋白质含量（9.23 g/100 g）远高于LRP(8.01 g/100 g),LR中灰分含量（3.90 g/100 g）较高于LRP(3.10 g/100 g),水分和粗纤维含量二者相差不大。LR和LRP中EAA/TAA分别为40.30%和43.98%,EAA/NEAA分别为67.48%和78.50%,∑n6 PUFA/∑n3 PUFA比值分别为0.13和0.12。同时,LR和LRP富含多种矿物质元素和维生素,LR中Ca含量（7 646.67 mg/kg）最高,LRP中K含量（5 576.67 mg/kg）最高,二者VE含量分别高达37.10 mg/100 g和27.50 mg/100 g。此外,LR和LRP主要活性成分为粗多糖、茶多酚、总黄酮和总皂苷,除茶多酚含量均为14.30 g/100 g以外,...     

Optical spectra and optical conductivities of iodine-doped polyacetylene

Reflection spectra of iodine-doped polyacetylene are studied for the wavenumber range 20–40 000 cm⁻¹ in order to find changes occurring in the electronic structure of the polymer upon doping. Three stages of doping are recognized from a spectral analysis of (CHI_y)_x : (1) 0 < y < 0.10, where the charged soliton domain is the dominant product; (2) 0.10 < y < 0.18, the free carrier is found where the hole and the unpaired electron are formed simultaneously; (3) 0.19 < y < 0.25, the free carriers begin to overlap each other and metallic properties become more evident. A new type of electronic transition associated with the electron transfer (charge resonance) between the hole states is found strongly in the far-infrared region. The origin of the metallic properties is discussed from a structural viewpoint.     

红外光谱技术在鱼产品质量检测与安全评估中的应用

近年来消费者对鱼产品的掺假问题愈发关注,从而针对鱼产品的质量评估的相关研究也逐渐增加。传统的鱼类成分分析和质量检测技术方法烦琐、费力、昂贵、费时,而光谱技术因其具有速度快、使用方便、样品制备最少或不需要样品制备,及避免样品破坏等优点而受到越来越多的关注。本文综述了以红外光谱技术为主的光谱技术,包括近红外光谱技术、中红外光谱技术等在鱼类及鱼产品的成分和其他质量特性监测中的应用,并对光谱技术的应用前景和发展方向进行了展望,以期为红外光谱技术在鱼类及鱼产品质量监测体系中推广应用提供指导,为解决鱼产品及相关行业的质量问题提供了一种新的途径。     

洞口形状对腹板开洞钢-混凝土组合梁的受力性能影响分析

通过研究洞口形状对腹板开洞钢-混凝土组合梁受力的影响,选择合适的洞口形状以降低开洞造成的不利影响;在已有试验基础上,利用ANSYS对洞口设置在弯剪区段且洞口形状不同的组合梁进行力学性能分析,研究了洞口形状对承载力、变形能力以及内力重分布和传力机制的影响。结果表明：钢-混凝土组合梁腹板开洞会导致刚度、极限承载力下降;非正方形洞口组合梁因洞口形状不同,极限变形有不同程度增强;洞口形状会影响洞口处混凝土、钢梁承担的剪力比例,混凝土占总剪力的46%～59%,而钢梁占总剪力的41%～54%;极限变形与洞口处塑性铰的面积大小有关;栓钉会对周围的混凝土产生一定预压力,对混凝土应力重分布有影响,洞口处混凝土的剪力有明显的剪力差,洞口下方钢梁所承受的剪力大于洞口上方钢梁;洞口形状会影响组合梁内部传力机制,长方形、正方形洞口试件在洞口区域以次弯矩传递力,非长方形、正方形洞口试件在洞口区域以主弯矩传递力;在结构设计时应该考虑洞口位置的偏心、主应力方向与洞口边缘的夹角。     

紫竹竹叶提取物作为盐酸中锌的缓蚀剂的研究

用失重法研究了紫竹(Phyllostachys nigra Munro)竹叶提取物PMLE在0.01~0.05 mol/LHCl溶液中对锌的缓蚀作用。结果表明:PMLE对锌在0.01 mol/LHCl溶液中具有良好的缓蚀作用,且在锌表面的吸附符合Langmuir吸附等温式。缓蚀率随缓蚀剂浓度的增加而增大,但随温度和盐酸浓度的增加而减小。通过Van't Hoff方程和Mathur经验动力学公式分别求出了吸附焓ΔHads和腐蚀动力学参数(速率常数k,动力学常数B),并据此参数讨论了PMLE的缓蚀行为。     

Inhibition effect of methyl violet on the corrosion of cold rolled steel in 1.0 M sulfuric acid solution

The inhibition effect of methyl violet (MV) on the corrosion of cold rolled steel (CRS) in 1.0 M sulfuric acid (H₂SO₄) was investigated by weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) methods. The results show that MV is a good inhibitor, and inhibition efficiency increases with inhibitor concentration, while decreases with the temperature. The adsorption of MV on CRS surface obeys Langmuir adsorption isotherm equation. The thermodynamic parameters of adsorption enthalpy (ΔH°), adsorption free energy (ΔG°) and adsorption entropy (ΔS°) are calculated and discussed. Potentiodynamic polarization curves show that MV acts as a mixed-type inhibitor in sulfuric acid. EIS exhibits one capacitive loop which indicates that the corrosion reaction is controlled by charge transfer process. Inhibition efficiency values obtained from weight loss, polarization and EIS are in reasonably good agreement. The adsorbed film on CRS surface containing optimum dose of MV was investigated by Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM). Depending on the results, the inhibitive mechanism is proposed from the viewpoint of adsorption theory.     

浅析英法哥特建筑的发展

哥特式建筑于11世纪开始登上历史舞台,它在这个舞台上闪耀了8个世纪,也影响了整个欧洲乃至全世界的建筑风格。文章就英法两国哥特式建筑风格在不同历史背景下的发展和形成原因进行对比分析,并挖掘其历史成因和文化内涵。     

Adsorption and inhibition effect of 6-benzylaminopurine on cold rolled steel in 1.0 M HCl

The adsorption and inhibition effect of 6-benzylaminopurine (BAP) on cold rolled steel (CRS) in 1.0 M HCl at 25-50 °C was studied by weight loss and potentiodynamic polarization methods. The results showed that BAP was a good inhibitor in 1.0 M HCl, and the inhibition efficiency (IE) increased with the inhibitor concentration. The adsorption of BAP on the CRS surface obeyed the Langmuir adsorption isotherm equation. Both thermodynamic parameters (adsorption heat ΔH⁰, adsorption free energy ΔG⁰ and adsorption entropy ΔS⁰) and kinetic parameters (apparent activation energy E_a and pre-exponential factor A) were calculated and discussed. Polarization curves showed that BAP acted as a mixed-type inhibitor in hydrochloric acid. Good agreement between weight loss and polarization methods was obtained. The adsorbed film on CRS surface containing optimum dose of BAP was investigated by Fourier transform infrared spectroscopy (FTIR) and atomic force microscope (AFM). Quantum chemical calculation was applied to elucidate the adsorption mode of the inhibitor molecule onto steel surface. Depending on the results, the inhibitive mechanism was proposed from the viewpoint of adsorption theory.     

Inhibition by tween-85 of the corrosion of cold rolled steel in 1.0?M hydrochloric acid solution

The inhibition effect of tween-85 on the corrosion of cold rolled steel (CRS) in 1.0 M hydrochloric acid (HCl) was studied by weight loss and potentiodynamic polarization methods. The results show that tween-85 is a good inhibitor in 1.0 M HCl and its maximum inhibition efficiency (IE) is 92% at very low concentration. Its adsorption obeys the Langmuir adsorption isotherm equation. The thermodynamic parameters of adsorption enthalpy (ΔH ⁰), adsorption free energy (ΔG ⁰) and adsorption entropy (ΔS ⁰) were calculated and discussed. Polarization curves show that tween-85 acts as a mixed-type inhibitor in hydrochloric acid. IE values obtained from weight loss and polarization are consistent. The adsorbed film on a CRS surface containing an optimum dose of tween-85 was investigated by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS) and atomic force microscope (AFM). An inhibitive mechanism is proposed from the viewpoint of adsorption theory.